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Abstract. Portable and core-scanning X-ray fluorescence (XRF) instruments have become increasingly utilized in making rapid, non-destructive chemical characterizations with high spatial resolution on a range of materials. Since basaltic cores are often highly fractured and uneven, portable XRF (pXRF) is preferred to conduct discrete chemical analyses. However, in this case, the user must select the location for each analysis, which can lead to biased datasets. Alternatively, XRF core-scanning (XRF-cs) instruments take a series of measurements along a section of core, increasing the number of analyses and, therefore, eliminating some of the bias introduced by discrete analyses conducted with a pXRF. The XRF-cs does, however, still require a flat sampling surface along the core that does not include void spaces, making rigid, vesicular, and often cracked basalts suboptimal targets. We collected 797 XRF-cs measurements on three basaltic cores collected during the International Ocean Discovery Program Expedition 396 to evaluate how effectively an XRF core scanner can build large, chemically representative datasets. We developed a method for filtering XRF-cs measurements and calibrated the data using discrete calibrated pXRF analyses and compared the XRF-cs data to pXRF and conventional bulk-rock data using various immobile (e.g., Al, Ti, Zr, Ni, Mn, Zn) and mobile (e.g., K, Ca, Sr) elements. The comparison between datasets shows that (1) the XRF-cs data reproduce trends observed by pXRF and conventional bulk-rock data at both the regional scale and the core scale, and (2) in some cases, the higher spatial resolution of the XRF-cs data reveals geochemical variations that are otherwise obscured using discrete analyses. The workflow outlined by this study can be used to select samples for future studies by efficiently providing reliable geochemical data for characterizing new and legacy hard-rock cores. 

New major and trace element data on samples collected during the IODP (International Ocean Discovery Program) Expedition 396, ODP (Ocean Drilling Program) Leg 104, and DSDP (Deep Sea Drilling Project) Leg 38 on the Vøring margin, including 209 whole rocks analyses on hard rock samples (basalt, granite, andesite, dacite and rhyolite), 13 whole rock data on ash layers, and 381 in situ pXRF analyses on basaltic rocks. The DIGIS geochemical data repository is a research data repository in the Earth Sciences domain with a specific focus on geochemical data. The repository archives, publishes and makes accessible user-contributed, peer-reviewed research data in standardised form (EarthChem Team, 2022, https://doi.org/10.26022/IEDA/112263) that fall within the scope of the GEOROC database (https://georoc.eu). All submissions of new data will be considered for inclusion in the GEOROC database. It is hosted at GFZ Data Services through a collaboration between the Digital Geochemical Data Infrastructure (DIGIS) for GEOROC 2.0 (https://digis.geo.uni-goettingen.de) and the GFZ Helmholtz Centre for Geosciences. 

The stability of the West Antarctic Ice Sheet (WAIS), crucial for predicting future sea-level rise, is threatened by ocean-forced melting in the Pacific sector of the Southern Ocean. While some geological records and ice-sheet models suggest WAIS retreat during past warm periods, reliable data constraining the extent of retreat are lacking. Detrital Nd, Sr, and Pb isotope data of sediments recently drilled at International Ocean Discovery Program (IODP) Site U1532 on the Amundsen Sea continental rise manifest repeated alternations in sediment provenance during glacial–interglacial cycles of the Pliocene (5.33 to 2.58 Mya), a time warmer than present. The variations reflect large fluctuations in WAIS extent on the Antarctic continent. A unique high Pb/low ε_Ndsignature of sediments found at the onset of glacial intervals (3.88, 3.6, and 3.33 Ma) is attributed to the supply of detritus sourced from plutonic rocks located in the West Antarctic interior. Its isotopic signature at Site U1532 indicates major inland retreat of the WAIS during the preceding interglacials. During peak interglacials, the ice margin had retreated inland, and icebergs rafted and deposited inland-sourced detritus over 500 km across the Amundsen Sea shelf. Subsequent readvance of grounded ice then “bulldozed” these inland-derived fine-grained sediments from the shelf down to the continental slope and rise, resulting in a high Pb/low ε_Ndpeak in the rise sediments. Our continuous Pliocene records provide conclusive evidence for at least five major inland retreat events of the WAIS, highlighting the significant vulnerability of the WAIS to ongoing warming. 

Abstract. With the onset of anthropogenic climate change, it is vital that we understand climate sensitivity and rates of change during periods of warming in the Earth's past to properly inform climate forecasts. To best inform modeling of ongoing and future changes, environmental conditions during past periods of extreme warmth are ideally developed from multiproxy approaches, including the development of novel proxies where traditional approaches fail. This study builds on a proposed sea surface temperature (SST) proxy for the high-latitude Southern Ocean, based on the morphometrics of the ubiquitous Antarctic diatom Fragilariopsis kerguelensis. This species has been shown to display two distinct morphotypes; a low-rectangularity morphotype is interpreted to be more common in warmer waters while a high-rectangularity morphotype is more common in cooler waters. The proportion of the low-rectangularity morphotype (pLR) has been correlated to SST and summer SST (SSST). Here, we examine this proxy by reconstructing SST using sediment samples from the modern seafloor surface in the Amundsen Sea and the Sabrina Coast to test how well two published calibrations of this relationship (Kloster et al., 2018; Glemser et al., 2019) reconstruct SST and SSST in the modern ocean. In the Amundsen Sea surface sediments, we calculate derived SST −1.6 to −1.2 °C and derived SSST 0.6 to 0.7 °C. In the Sabrina Coast surface sediments, we calculate derived SST −0.3 to 0.5 °C and derived SSST 1.4 to 2.5 °C. We discuss the differing population dynamics of F. kerguelensis in our surface samples between the Amundsen Sea and Sabrina Coast because the Amundsen Sea specimens display a lower pLR than Sabrina Coast specimens, although they exist in warmer waters and should display a higher pLR. We also use the two published calibrations to preliminarily reconstruct SST and SSST in the Amundsen Sea over the last interglacial, Marine Isotope Stage 5 (MIS-5). We calculate SSTs that are slightly cooler or within the range of the modern Amundsen Sea for the duration of the last interglacial; we calculate summer SSTs ∼ 1 °C warmer than the modern Amundsen Sea. This suggests MIS-5 SSTs were at most marginally warmer than the modern Amundsen Sea. 

The mid-Norwegian margin is one of the best studied volcanic rifted margin on Earth. Geophysical investigations have demonstrated the presence of well-developed seaward-dipping reflectors, landward-dipping reflectors, marginal highs, ash layers and sill complexes. These features have been proven to consist of magmatic rocks through the international Deep Sea Drilling Program (DSDP expedition 38, 1974), Ocean Drilling Program (ODP expedition 104, 1985), International Discovery Program (IODP expedition 396, 2021), and commercial drilling. A total of fifteen drill cores penetrated magmatic rocks that formed between 57 and 50 million-years ago. Here we provide a compilation of all new and published data for magmatic rocks in the fifteen drill cores (n= 563). This dataset represent a resource for examining the origin of magmatism associated with continental breakup and rifted margin formation, particularly the formation of excess magmatism compared to normal mid-oceanic spreading ridges, mantle-crust interaction, and the linkage of magmatism to global hyperthermal events on Earth’s surface. The DIGIS geochemical data repository is a research data repository in the Earth Sciences domain with a specific focus on geochemical data. It is hosted at GFZ Data Services through a collaboration between the Digital Geochemical Data Infrastructure (DIGIS) for GEOROC 2.0 (https://digis.geo.uni-goettingen.de) and the GFZ Helmholtz Centre for Geosciences. The repository archives, publishes and makes accessible user-contributed, peer-reviewed research data that fall within the scope of the GEOROC database. Compilations of previously published data are also made available on the GEOROC website (https://georoc.eu) as Expert Datasets. 

Abstract The mid‐Norwegian Margin, part of the North Atlantic Igneous Province (NAIP), is a well‐studied volcanic rifted margin formed during the breakup between Greenland and Eurasia ∼56 Ma, with the largest accumulation of magmatic material hosted by the Vøring Margin section. Despite extensive study in the area, the main controls on magmatic productivity during continental breakup remain debated. To constrain the drivers of breakup magmatism, we developed an inverse Monte Carlo statistical melting model that infers source mineralogy from basalt chemistry. When applied to basalts recently recovered on the Vøring Margin, our results reveal a clear shift in source mineralogy during rifting, with peak magmatism coinciding with clinopyroxene enrichment, despite mantle potential temperatures likely being capped below 1500°C. We also establish that, while the proto‐Iceland mantle plume played a role during the emplacement of the NAIP, the main driver for the continental breakup magmatism is lithospheric thinning as a consequence of continent breakup. This study provides new insights into the magmatic and geodynamic evolution of the mid‐Norwegian Margin, emphasizing the role of lithospheric refertilization in driving breakup magmatism. 

Abstract. Knowledge of past ice sheet configurations is useful for informing projections of future ice sheet dynamics and for calibrating ice sheet models. The topology of grounding line retreat in the Ross Sea sector of Antarctica has been much debated, but it has generally been assumed that the modern ice sheet is as small as it has been for more than 100 000 years (Conway et al., 1999; Lee et al., 2017; Lowry et al., 2019; McKay et al., 2016; Scherer et al., 1998). Recent findings suggest that the West Antarctic Ice Sheet (WAIS) grounding line retreated beyond its current location earlier in the Holocene and subsequently readvanced to reach its modern position (Bradley et al., 2015; Kingslake et al., 2018). Here, we further constrain the post-LGM (Last Glacial Maximum) grounding line retreat and readvance in the Ross Sea sector using a two-phase model of radiocarbon input and decay in subglacial sediments from six sub-ice sampling locations. In addition, we reinterpret high basal temperature gradients, measured previously at three sites in this region (Engelhardt, 2004), which we explain as resulting from recent ice shelf re-grounding accompanying grounding line readvance. Atone location – Whillans Subglacial Lake (SLW) – for which a sedimentporewater chemistry profile is known, we estimate the grounding linereadvance by simulating ionic diffusion. Collectively, our analyses indicate that the grounding line retreated over SLW 4300-2500+1500 years ago, and over sites on Whillans Ice Stream (WIS), Kamb Ice Stream (KIS), and Bindschadler Ice Stream (BIS) 4700-2300+1500, 1800-700+2700, and 1700-600+2800 years ago, respectively. The grounding line only recently readvanced back over those sites 1100-100+200, 1500-200+500, 1000-300+200, and 800±100 years ago for SLW, WIS, KIS, and BIS, respectively. The timing of grounding line retreat coincided with a warm period in the mid-Holocene to late Holocene. Conversely, grounding line readvance is coincident with cooling climate in the last 1000–2000 years. Our estimates for the timing of grounding line retreat and readvance are also consistent with relatively low carbon-to-nitrogen ratios measured in our subglacial sediment samples (suggesting a marine source of organic matter) and with the lack of grounding zone wedges in front of modern grounding lines. Based on these results, we propose that the Siple Coast grounding line motions in the mid-Holocene to late Holocene were primarily driven by relatively modest changes in regional climate, rather than by ice sheet dynamics and glacioisostatic rebound, as hypothesized previously (Kingslake et al., 2018). 

High-resolution, well-dated climate archives provide an opportunity to investigate the dynamic interactions of climate patterns relevant for future projections. Here, we present data from a new, annually dated ice core record from the eastern Ross Sea, named the Roosevelt Island Climate Evolution (RICE) ice core. Comparison of this record with climate reanalysis data for the 1979–2012 interval shows that RICE reliably captures temperature and snow precipitation variability in the region. Trends over the past 2700 years in RICE are shown to be distinct from those in West Antarctica and the western Ross Sea captured by other ice cores. For most of this interval, the eastern Ross Sea was warming (or showing isotopic enrichment for other reasons), with increased snow accumulation and perhaps decreased sea ice concentration. However, West Antarctica cooled and the western Ross Sea showed no significant isotope temperature trend. This pattern here is referred to as the Ross Sea Dipole. Notably, during the Little Ice Age, West Antarctica and the western Ross Sea experienced colder than average temperatures, while the eastern Ross Sea underwent a period of warming or increased isotopic enrichment. From the 17th century onwards, this dipole relationship changed. All three regions show current warming, with snow accumulation declining in West Antarctica and the eastern Ross Sea but increasing in the western Ross Sea. We interpret this pattern as reflecting an increase in sea ice in the eastern Ross Sea with perhaps the establishment of a modern Roosevelt Island polynya as a local moisture source for RICE.